Taste a lemon straight and your face does the work for you. Taste that same juice spread through 400 g of sweetened gelatin and it nearly disappears. Dilution is the whole story. A batch this size holds 45 g of juice, which works out at barely 2 g of real acid. To match a commercial sour bear on juice alone you would need roughly a third of the batch weight in juice. Gelatin will not set against that much water at that low a pH, so the recipe collapses before the flavour arrives.
Citric acid is the shortcut. It is the same acid the lemon already contains, sold dry, and 4 g of it carries further than 80 g of juice. The juice still goes in, because it brings a fruit flavour the powder has none of. It just stops being the thing doing the sour.



